Oxidative stress is considered an etiological factor responsible for several symptoms of inflammatory bowel disease (IBD). In vitro anti-inflammatory activities of heat-killed Lactococcus lactis subsp. lactis BF3 have been reported. In this study, the anti-inflammatory effect of these cells was examined using a dextran sodium sulphate (DSS)-induced murine IBD model. Administration of heat-kille...

We have observed several IR bands of CH3CN-BF3 in neon and nitrogen matrices. For the 11B isotopomer in neon matrices, we observed the BF3 symmetric deformation band (nu7) as a doublet at 600 and 603 cm(-1), the BF3 symmetric stretching band (nu6) as a doublet at 833 and 838 cm(-1), the BF3 asymmetric stretching mode (nu13) at 1281 cm(-1) (partially obscured), and the C-N stretching mode (nu2) ...

Treatment of the imine PhC(=NSiMe3)py with Et2BOMe or BF3·Et2O afforded bicyclic ketiminoboranes and via intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of ·HCl and ·BF3 are reported as well as the dipyridyl imine derivative ·HCl.

The complexes [BX3(m-L L)BX3] (X 1⁄4 Cl, Br, I; L L 1⁄4 EtS(CH2)2SEt, MeSe(CH2)2SeMe), [BX03{oC6H4(SMe)2}] (X’ 1⁄4 Cl, I), [(BBr3)2{o-C6H4(SMe)2}], [(BBr3)2{o-C6H4(SeMe)2}] and [BI3{o-C6H4(SeMe)2}] have been prepared as moisture-sensitive pale solids by reaction of the appropriate BX3 with the dichalcogenoether in anhydrous n-hexane solution, and characterised by microanalysis, IR and multinucl...

A six-membered N-heterocyclic carbene fused with a spiro-scaffold is designed. The new NHC shows stronger σ-donation ability than typical 5-membered NHCs. This property leads to interesting reactivities of this spiro-fused six-membered NHC. For example, the NHC-BF3 Lewis pair complex can be readily prepared by using LiBF4 as the BF3 source, or through a direct bond-reconstruction of the tetrafl...

The saturation vapour pressure of {x BF3 + (1−x)n-C4H10} has been measured at 195.49 K. The system shows large positive deviations from Raoult’s law and liquid–liquid immiscibility over a wide composition range whose limits have been estimated as 0.39±0.03 < x > 0.9785. The excess molar Gibbs energies (Gm) have been calculated as a function of composition from the vapour pressure data. For the ...